In situ time resolved synchrotron powder diffraction study of thaumasite     

Annalisa Martucci  Giuseppe Cruciani 《Physics and Chemistry of Minerals》2006,33(10):723-731

Structural changes during dehydration and subsequent decomposition in thaumasite Ca₃Si(SO₄)(CO₃)(OH)₆·12 H₂O were studied by in situ synchrotron powder diffraction between 303 and 1,098 K. Evolution of the crystal structure was observed through 28 structure refinements, by full profile Rietveld analysis performed in the P6₃ space group, between 300 and 417 K, whereupon the thaumasite structure was observed to breakdown. Within this temperature range, the cell parameters of thaumasite increased as a function of temperature in a nearly linear fashion up to about 393 K, at which temperature, a slight slope change was observed. Above 400 K, the thermogravimetric analysis revealed that the dehydration process proceeded very rapidly while the refined occupancy of water molecules dropped below a critical level, leading to instability in the thaumasite structure. At a same time, a remarkable change in the unit cell parameters occurring at about 417 K indicated that the crystal structure of thaumasite collapsed on losing the crystallization water and it turned amorphous. This result indicated that the dehydration/decomposition of thaumasite was induced by the departure of the crystallization water. At about 950 K, anhydrite and cristobalite crystallized from the thaumasite glass.  相似文献   

Groundwater study using remote sensing and geographic information systems (GIS) in the central highlands of Eritrea   总被引：3，自引：1，他引：3  

Semere Solomon  Friedrich Quiel 《Hydrogeology Journal》2006,14(6):1029-1041

Remote sensing, evaluation of digital elevation models (DEM), geographic information systems (GIS) and fieldwork techniques were combined to study the groundwater conditions in Eritrea. Remote sensing data were interpreted to produce lithological and lineament maps. DEM was used for lineament and geomorphologic mapping. Field studies permitted the study of structures and correlated them with lineament interpretations. Hydrogeological setting of springs and wells were investigated in the field, from well logs and pumping test data. All thematic layers were integrated and analysed in a GIS. Results show that groundwater occurrence is controlled by lithology, structures and landforms. Highest yields occur in basaltic rocks and are due to primary and secondary porosities. High yielding wells and springs are often related to large lineaments, lineament intersections and corresponding structural features. In metamorphic and igneous intrusive rocks with rugged landforms, groundwater occurs mainly in drainage channels with valley fill deposits. Zones of very good groundwater potential are characteristic for basaltic layers overlying lateritized crystalline rocks, flat topography with dense lineaments and structurally controlled drainage channels with valley fill deposits. The overall results demonstrate that the use of remote sensing and GIS provide potentially powerful tools to study groundwater resources and design a suitable exploration plan.The online version of the original article can be found at  相似文献   

A Practical Procedure for the Measurement of Fragmentation by Blasting by Image Analysis   总被引：1，自引：0，他引：1  

J. A. Sanchidrián  P. Segarra  L. M. López 《Rock Mechanics and Rock Engineering》2006,39(4):359-382

Summary. The operation of a digital image analysis system in a limestone quarry is described. The calibration of the system, required in order to obtain moderately reliable fragmentation values, is done from muckpile sieving data by tuning the image analysis software settings so that the fragmentation curve obtained matches as close as possible the sieving. The sieving data have also been used to extend the fragment size distribution curves measured to sizes below the system’s optical resolution and to process the results in terms of fragmented rock, discounting the material coming from a loose overburden (natural fines) that is cast together with the fragmented rock. Automatic and manual operation modes of the image analysis are compared. The total fragmentation of a blast is obtained from the analysis of twenty photographs; a criterion for the elimination of outlier photographs has been adopted using a robust statistic. The limitations of the measurement system due to sampling, image processing and fines corrections are discussed and the errors estimated whenever possible. An analysis of consistency of the results based on the known amount of natural fines is made. Blasts with large differences in the amount of fines require a differentiated treatment, as the fine sizes tend to be the more underestimated in the image analysis as they become more abundant; this has been accomplished by means of a variable fines adjustment factor. Despite of the unavoidable errors and the large dispersion always associated with large-scale rock blasting data, the system is sensitive to relative changes in fragmentation.  相似文献   

Damage Survey of Water Supply Systems and Fragility Curve of PVC Water Pipelines in the Chi–Chi Taiwan Earthquake     

Ban-Jwu Shih  Che-Hao Chang 《Natural Hazards》2006,37(1-2):71-85

Substantial damage to water supply systems, including water delivery pipelines, water treatment plants, reservoirs, and water storage tanks, was reported after the 1999 Chi–Chi Taiwan Earthquake. This paper first summarizes the damage survey and then presents the results of seismic fragility analysis for underground pipelines. Construction blueprints of the water delivery pipelines and repair work orders of 11 townships and cities in the disastrous area were digitized into a Geographical Information System (GIS) for analysis and assessment. With the aid of the GIS system, we found that PVC pipes made up 86% of water delivery pipelines while steel, cast iron, ductile iron, PE and others took the rest. Therefore, this paper focuses on the fragility analysis of PVC pipes. Three different methods were applied to derive the fragility relations between the PVC water pipes having nominal diameters (approximately inner diameters) greater than or equal to 65 mm and earthquake intensity parameters such as peak ground acceleration and peak ground velocity. The results were then examined with those of other countries. The discrepancy between our results and the empirical equation used by HAZUS, an earthquake loss estimation software developed by the Federal Emergency Management Agency was not significant.  相似文献   

Biofacies of Upper Jurassic and Lower Cretaceous sediments of central West Siberia     

V. A. Marinov  S. V. Meledina  O. S. Dzyuba  O. S. Urman  O. V. Yazikova  V. A. Luchinina  A. G. Zamirailova  A. N. Fomin 《Stratigraphy and Geological Correlation》2006,14(4):418-432

Paleontological study of Upper Jurassic and Lower Cretaceous sediments recovered by boreholes in the Agan-Vakh and Nadym-Vengapur interfluves clarified environments of their deposition. As is shown, influx of siliciclastic material to central areas of the West Siberian sea basin varied through time. Taxonomic composition and ecological structure of nektonic and benthic fossil assemblages are analyzed and considered in terms of environmental factors such as hydrodynamics, aeration, temperature, and salinity of seawater.  相似文献   

Effect of a submerged bay-mouth breakwater on tsunami behavior analyzed by 2D/3D hybrid model simulation     

Koji Fujima 《Natural Hazards》2006,39(2):179-193

The hybrid numerical model had been developed to simulate a complicated 3D flow around structures generated by tsunami. In the model, the conventional 2D model is adopted for the wide region far from structures and the 3D non-hydrostatic pressure model is used in the limited region adjacent to structures. The applicability of the model is shown by comparisons of the numerical results with the experimental results of the laboratory model tests and the numerical analysis results of the conventional whole 2D simulation. In addition, the effect of a submerged structure at the opening of a breakwater is discussed from the numerical simulations by the hybrid model. The submerged structure improves the stability of the rubble mound and reduces the tsunami inflow into the bay, while it increases the water surface velocity around the opening of the breakwater. The increase of surface velocity causes the increases of impulsive forces by collision with drafts and so on.  相似文献   

Assessing the Vibrational Frequencies of the Cathedral of Cologne (Germany) by Means of Ambient Seismic Noise Analysis   总被引：1，自引：0，他引：1  

Andreas Fäcke  Stefano Parolai  Sandra M. Richwalski  Lothar Stempniewski 《Natural Hazards》2006,38(1-2):229-236

Ambient seismic noise measurements were conducted inside the Cathedral of Cologne (Germany) for assessing its frequencies of vibration and for checking whether these occur in the range where soil amplification is expected. If this is the case, damages may increase in case of an earthquake due to an increased structural response of the building. Analysis of the ratio between the horizontal and vertical components of the spectra recorded at stations located inside the building as well as the ratio between the corresponding components of the spectra recorded simultaneously inside the building and at a reference station placed in the basement of the cathedral indicated several modes of vibration. Facilitated by these results an assessment of the seismic vulnerability was attempted for a 2D ground motion scenario using the finite element method.  相似文献   

Real Time Analysis and Forecasting of Strata Caving Behaviour during Longwall Operations     

S. Tadisetty  K. Matsui  H. Shimada  R. N. Gupta 《Rock Mechanics and Rock Engineering》2006,39(4):383-393

Summary. Discontinuous manual observations and irregular caving characteristics of roof rocks often lead to improper decisions resulting in accidents and production loss. Hence, systematic monitoring of the hanging roof behind the chock shields is necessary for safe and productive mining operations. A real-time application was successfully implemented in an Indian mine for forecasting of hanging roof behaviour to enhance safety and productivity. This paper reports the functioning of real-time TWAP (time weighted average pressure) analysis in the forecasting of hanging roof behaviour in real time.  相似文献   

T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1     

Jo R?islien  Henning Omre 《Mathematical Geology》2006,38(7):821-849

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.  相似文献   

Risk assessment of groundwater pollution using sensitivity analysis and a worst-case scenario analysis   总被引：5，自引：0，他引：5  

Marijke Huysmans  Tamás Madarász  Alain Dassargues 《Environmental Geology》2006,50(2):180-193

This paper illustrates how sensitivity analysis and a worst-case scenario analysis can be useful tools in risk assessment of groundwater pollution. The approach is applied to a study area in Hungary with several known groundwater pollution sources and nearby drinking water production wells. The main concern is whether the contamination sources threaten the drinking water wells of the area. A groundwater flow and transport model is set up to answer this question. Due to limited data availability, the results of this model are associated with large uncertainty. Sensitivity analysis and a worst-case scenario analysis are applied to estimate this uncertainty and build confidence in the model results.  相似文献